OBJECTIVE: To evaluate the bleaching efficacy and hydrogen peroxide (HP) permeability of whitening pens, with and without light-activation systems. Also, pulp temperature and physicochemical properties were assessed, as well as the characterization of the light sources. MATERIAL AND METHODS: Ninety premolars were distributed into nine groups (n = 10): untreated, Colgate Optic White Pen ComfortFit LED (CF), Colgate Optic White Pen Express (CX), Equate Teeth Whitening Kit (EW) and Zimba Teeth Whitening Kit (ZW), with and without light-activation. Bleaching efficacy (WI(D), DeltaE(ab), and DeltaE(00)) was assessed using a digital spectrophotometer. HP permeability (mug/mL) was measured by UV-Vis; initial concentration (%), pH, and pulp temperature variation (DeltaT, degrees C) by titration, pH meter, and T-type thermocouple, respectively. Light characteristics were determined using spectroradiometer and integrating sphere. Statistical analysis included ANOVA, Tukey's, and Dunnett's tests (alpha = 0.05). RESULTS: ZW light device exhibited the highest power and irradiance (p < 0.05). EW and ZW emitted blue light (peak: 456 nm), while CF device emitted violet light (peak: 405 nm). Light-activation did not significantly impact WI(D) or HP permeability (p > 0.05). However, CF and CX showed greater color changes under light, when evaluated by DeltaE(ab)/DeltaE(00) (p < 0.05). All groups showed acidic pH; EW and ZW exhibited the highest HP concentration and permeability (p < 0.05). Pulpal temperature variations were not significant across groups (p > 0.05). CONCLUSIONS: Light-activation had no significant impact on bleaching efficacy (WI(D)) or HP permeability, regardless of HP concentration or pH. CLINICAL SIGNIFICANCE: It is not essential to combine light devices with whitening pens to achieve bleaching efficacy.
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